I do not think that is her.
James Quilliam married Elizabeth Cringal; 01 Apr 1871
They had these children"
Catharine A Quilliam 16 Jul 1871 Patrick
John James Quilliam 22 Dec 1872
Louisa Quilliam 27 Sep 1874
Elizabeth Quilliam 1876, from census info
Lawrence Quilliam 1878, from census info
Emily Quilliam 1880, from census info
Elizabeth Cringal died and James Quilliam re-married to Frances or Fanny Karran 07 Jan 1883
Robert Quilliam 1886
Thomas Quilliam
Louisa Quilliam went to Leeds & married John Dickinson,
Have found what happened with rest of children, lost track of Catharine A Quilliam after 1881.
Tim